I'm trying to avoid spoilers as much as possible as I've only progressed a limited amount into the game. That being said, I don't want to miss-out on any of the SPECIAL Bobbleheads. My intention is to max-out a given SPECIAL to 10 BEFORE picking up it's corresponding Bobblehead, thereby pushing that SPECIAL to 11. So my question is, are any of the SPECIAL Bobbleheads accessible one time only, where if you don't pick it up right then and there, you miss-out on it forever? I don't want to know where any are located, or which quest they may or may not be associated with, just which ones, if any, this may pertain to...

Thanks in advance!

nope, only cha bobblehead requires a quest to start everything else is freely available.

If you're going for all of the magazines, too, make sure you find the copy of Astoundingly Awesome Tales in the Institute before completing the Nuclear Option. That's the only permanently missable magazine I know of.