When buying cards for your caravan deck, they will just sit in your inventory and you won't be able to add them to your deck. This is fixed by putting the cards into any container, then retrieving them. The cards then go straight into your deck. (Note: There is a workaround for this bug. If you place the cards in a container and then remove them from the container one at a time, they are then added to your caravan deck. Similarly, placing them in a companion's inventory and removing them also adds the cards to your deck.) - vault wiki
supposedly this is only a PC issue but this happened to me when i made a new save with the patch applied. it's pretty annoying