Until issues are sorted with the Save synchronization, the Cloud Service with Steam has been disabled. There has been no announcement as to when it will return, if ever.
One thing I will caution you on, if there are mods on one build and not the other, or the mod mix is not exactly the same between the two builds, you will hose your save going from one to the other and back again. Vanilla Games are OK. Not sure as to how much effect the different pre-order bonuses will have on this, but that could be an issue too.