The one you picked up in Klamath has nothing to do with the reactor. Whether it should be or not I'm not sure, though the Enclave is somewhat tied to the reactor, if only for flavour purposes. That key may have been originally designed to be used at the plant, but was possibly left out of the final cut. You can find a yellow key card in Gecko, possibly in the plant itself, have a look around. Also try to open the door, unlocking doesn't combine an open command, you need to unlock, then open.
As for the forms, you need to be authorised them, of course, you have no reason to obtain authorisation, so you need to steal them. Have a look around in that building Harold is in.