From my understanding, all fortifies work on followers. However I think it's wasted to give them a fortify block when the follower can't really die from enemy attacks. I just always give them something that increases their damage (fortify destruction, one-handed, two-handed, etc) or a fortify that benefits me (restoration, strength).
They are already packmules, so you can have them wear all fortify strength equipment to become even more so as well.