It happens to BoS, Outcast, and Enclave NPCs, and on all the variants of power armor.
The glowing purple power armor is noticeable both while the NPC is alive and dead, but the flickering usually only begins after the NPC is killed.
I will try to get some screen shots of the "glowing purple" effect, but usually, when I'm engaging power armor clad foes, I'm using hit and run tactics...