Double-face bug happens when you fast travel with a follower. UOP provides an "on touch" spell to cure it, and adds it to your list.
IIRC you can do the same thing with either kill/resurrect commands or disable/enable via console, but there may be side-effects of doing those with some characters. E.g. if you kill Martin the game ends before you can resurrect him.
It may also go away if you leave the cell they're in and re-enter, which is only useful if you can go outside/inside without them following.