Probably a quest-centric NPC, if he's one of the prisoners I wouldn't worry about it too much. You can always resurrect him via console command if you're on PC.
Actually from what I can tell he's one of the Powder Gangers. I'm not sure if he was auto-hostile though as I was firing on manual.
Heh, just killed another one named Scrambler, I think and go "Quest Failed: I Fought The Law." Guess i just slaughtered a quest hub, if I'd supported the Powder Gangers. Kewl!
EDIT: Welp, just found the answer. Meyer was a prisoner there, and one of the options for a new sheriff for a nearby town. Oops.