"Our patrols are always picking up new things,"
Seeing as there are no patrols given McNamara's lockdown protocols!
-RRR: So, Bethesda, how do you explain this incongruity?
-B: Oops! Our bad! I salute RRR's keen intellect on our mistake though! Here's a 12.7mm bullet on us. Put it through the head of a super mutant for us!
Honestly though, lets play the apologist game and try to rationalize what these "patrols" are and how Knight Torres is getting supplies, not to mention why she'd sell anything at all. It's not like the Brotherhood deal in the uncouth tender of *raises nose snobbishly* bottle caps *condescending, British, parlor laugh* aha... aha... aha...
Do Brotherhood members even need to buy things from quartermasters? They're a communal technotheocracy, not the Marine Corps. Even if some chapters did force their members to pay for supplies, I doubt the supplies in question would stretch beyond energy weapons, power cells, hydraulic fluid, and spare servos.
For some chapters, it makes sense, such as Lyons' Brotherhood, which its condition of ultimate heresy *gasp* lets outsiders join. With these kinds of uneducated conscripts, it would probably be necessary to stock a bunch of non-energy weapons and low-tech armor.