Nothing's easier than being sneaky. Sneak can be worked up easily as either a minor or a major skill. However, to get good critical hits you also need a high weapon skill and high strength or high agility also help. All these things can detract from your magic skills. The critical hit bonus applies only to your base weapon damage, not to additional damage from poison or enchants. You could do something like:
Altmer
Magic Specialization
Blade, Restoration, Sneak, Acrobatics, Mysticism, Mercantile, Speechcraft
You'd primarily focus on Blade and Sneak as major skills. The minor magic skills, even Destruction, can be increased as you like. I would not advise using this build if you're interested in using a bow. There's a lot of other possibilities, of course.
Mara