In Fallout 3/New Vegas, the price of the items you are buying or selling are directly tied to your barter skill and your Charisma stat. There is no haggling and no need to guess the optimal buying and selling price for a merchant.
Is there a mod that can automatically set the prices of items being bought or sold to their optimal values (depending on the character and the merchant's Mercantile skill and disposition) and without the need to haggle?