I think you mean a station devoted to classical music, since the music from Excalibur is from a mixture of periods. Been years since I last saw the movie, but I recall a good bit of Richard Wagner, who is solidly in the Romantic era. I remember a chunk for Carmina Burana, which is indeed based on early music but is itself composed in 1935, making it a fairly modern work. There are still a decent number of classical music radio stations in existence, but not nearly so many as there once were. Most of the better ones will have an internet presence. I've not listened to it in ages, but KUSC was at one time as good as any of 'em, and better than most. Whether it meets your needs I do not know, but you might give it a try.
BTW, there is more classical music at YouTube than you can shake a stick at. Like much else, it's just a matter of knowing how to search out what interests you. Here, for instance, is https://www.youtube.com/watch?v=2fdNBjCBpaA from Wagner's Gotterdammerung, which is heard a number of times in Excalibur. https://www.youtube.com/watch?v=wu3x_F06JlQ, though I don't believe this one appears in the movie.
If it be Medieval era music ye seek, https://www.youtube.com/watch?v=6GRLRm9oKUM.