Where can i buy all the good lockpicks such as grand lock pick?

Firstly, six posts have gone away, if all you can do is spend time making extremely rude and unnecessary posts using Let Me Google That For You, then don't bother posting.

Secondly a link straight to the UESP with the information, http://www.uesp.net/wiki/Morrowind:Thieves_Tools_Merchants, is all that is required.

AceStyler - Grand Master picks are difficult to come by although they will start showing up as you gain higher levels. You can get two of them that are always present either in Endusal, Karnac's study - not easy to get at, or Balmora Lucky Lockup - needs careful stealing.