I dont believe that you can move the individual save folder, and still keep the game so its able to see them.
However, you can move your entire My Documents folder. I moved mine to my H drive to save some space. To do this:
Go to C:\Users\(your username)
Right click on the My Documents folder and choose properties
Move over to the "Location tab"
Choose your new location.
The OS should now move everything over and see the new location as the correct place for My Documents from now on.