Is there anyway to keep the FOV at 90 or anything above the default? Kinda kills immersion and is flat out annoying to change it everytime I talk to an NPC?

Have you tried typing fov 90 in your console?

I have and it works, but when I talk to any NPC, it resets back to 75

Alright, how 'bout this. First type fov 90 into your console. Then type saveini into your console. See if that works. (The saveini command usually "locks in" any changes you make to your .ini settings).

Same line or separate command?

No, they're separate commands. So you will want to type one, hit Enter, then type the second one and hit Enter a second time. Then exit the console.

That worked. Thank you again, you've been quite helpful today.