I've actually watched a vid on youtube where the poster was using the console to pit a deathclaw against a behemoth. They fought several times, but I don't recall seeing the behemoth win a single fight. Simply put, the deathclaw and its attack were too fast for the behemoth to cope with. It always resulted in the deathclaw getting in the first shot which interrupted the behemoths attack.
The one I saw was a best of 3 match. DC won 2-1.