Everyone knows the dungeons/caves etc in vanilla oblivion are a little, uh, samey, so I was just wondering if there are any mods about that make dungeons a little more unique? Had a good ol' search around but couldn't find anything...
Not really. There was a project aiming at this once upon a time, but the only ones released were http://www.tesnexus.com/downloads/file.php?id=13939 and http://www.tesnexus.com/downloads/file.php?id=14036 IIRC. There's also a WIP just started: http://www.gamesas.com/index.php?/topic/1156767-dungeon-overhaul/.
And, of course, OOO makes dungeons a bit more unique by adding new enemy factions, bosses, items etc., but it's not a dungeon overhaul per se and does a lot of other things as well.