I always thought they were being sarcastic when they were speaking to you.
That's not the impression I got from the tone they use.
But anyway, it seems like little quirks like this are pretty common in Fallout 3's robots, the whispered remarks of your robot butler in either house for example "Not that I really want to." after asking how to help the player, for example. Or Cerberus, already mentioned in this thread, it seems that what the personae of Fallout robots want is not always compatible with what they are programed to do, I guess those simulated personalities weren't such a good idea.
Although in the case of Robobrains, it might be a fault of the organic brains they use rather than their programming, even if they were taken from criminals, it still is possible that their brains don't really want to do the things their programming makes them do.
The Sentry Bots and Protectrons and most Mr. Gutsies seem pretty dedicated to their missions though, but Mr. Gutsy and Protectron types have their own quirks, like the Protectrons' tendency to put unnecessary emphasis on certain words, or Mr. Gutsies sounding like an over the top representation of your stereotypical American military type.