Can some one help me produce a decent smooth talker? None of the builds I set off with seem to work. If possible I want High Luck, High Charisma, High Agility, and Decent Perception.

so what is stopping you? you can get implants for each special. plus you can raise them when you level up.

Best advice, drop strength and agility down to 3.
Raise those others up, tag small frame as a trait to give you a extra point in agility.
Use either..
9mm's, caravan shot guns, varmit rifles, service rifles and .357 revolvers or..
Energy weapons, as you'll suffer no penalties with your lower strength on these guns.

Get a companion early and untill then stay out of fights as much as possible.