Im new to the whole pc gaming and when i go to print screen in game it goes enable screenshots=1 in general in the ini file. where is this and how do i do it, please help thank you!

Open up Morrowind.ini, it's in the game's main folder, locate Screen Shot Enable=0 and change it to 1.

Cool thanks.

Or an even easier and better way (if you ask me). Use FRAPS

Even easier way is MGE, you do not even need to start it every time like fraps.