Three have been released, Dead Money, Honest Hearts and Old World Blues.
I think Dead Money is best because of the story, the atmosphere, the gear, the perks, the survival aspect, the new challenges it brings, the characters, the quest design, the choices, the backstory and the new home.
Honest Hearts and Old World Blues on the other hand are just two sandbox maps with fetch quests that desperately try to provide a good story but fail horribly.
They're both way too linear IMO.