I'm sure I read about it in the documentation, but I can't find it for some reason.
Well, it's directly at the top of the documentation... not sure how you missed it.
http://wryemusings.com/Wrye%20Mash.html
Lastly, can I re-order them without messing up my save game?
Yes.
After making the changes, just Update/Re-Sync your save file. Repairing it is also a good idea.
Don't know how to do those things? No worries, the Mash doc has all the info.
Having the Code Patch installed can also alleviate some problems associated with altering mods mid-game. But keeping your save files updated with Mash is a good habit.