I've pretty much finished all quests on my log and I'm sure there are some random quests out there I haven't seen. Is it possible to get an arrow in quests not handed out?

Not on console that I know of. Just go to inn keepers.

Why don't you just buy the game manual? If you you don't care for the spoilers, you don't have to go far---a list of all the quests (and factions that give them) that you're likiely missing out on is listed on the 2nd and 3rd pages of the game guide :biggrin: