Ooh I see. That's what all those things are for

You will need to use a weapon enchanted with soultrap or a soultrap spell to fill a soulgem.
Only black soulgems can hold souls of any of the playable races.
The rest are white souls and can be trapped in normal soulgems.
A soul will go in its lowest available container, a petty soul will go into a petty soulgem if you have one, a higher one if you only have those.