Buy only as far as I know. After the companion missions with Kodlak Eorlund says he thinks it hotter then it ever has been and you can make some new stuff, pretty much taking the weapons fo the Dragur, cleaning them up and such. But haven't seen the option to make Skyforge Steel weapons. Guess Eorlund is the only one with the recipe for making that particular steel
Was still a sad day when I had to hang up my Legendary Skyforge Steel Greatsword of Damnation. 110 damage and filled a soul gem if target died within 8 seconds. With all my perks everything usually died in 2 power swings. But, made Daedric and the numbers were too hard to ignore