It isn't the lack of plant life that kills the immersion for me, it's the inconsistencies that do it. I just feel that if Todd Howard wanted most of the buildings intact then he could have come with an excuse like DC, being the capital, had extremely good anti air protection and thus it was saved from the majority of missiles though sabotage by Chinese spies disguised as workers at a local food processing plant(Mama Dolce's) caused some of the missiles to break through its defenses which caused the deaths of the majority of the population and the destruction of some of its buildings.
Instead the only explanation we get from Bethesda is that it would be boring if it was all just sand and rubble so they took more then a few liberties with science and the lore. The truth is that I wouldn't be so annoyed with all of the inconsistencies if they had just given an explanation as to why, but it seems that Bethesda wasn't even willing to do that.
I did not follow the pre-release stuff frankly, and what I said earlier I heard later on this forum. True, the most likely scenario is that Bethesda never directly explained how D.C. is not entirely destroyed, but I don't see a real problem with that.
It seems nitpicky and focusing on the wrong detail.
The West Coast didn't just progress in the 23rd century. They had quite a large towns, trade routes and other crap only a couple decades after the Great War. The Great Merchant Wars in the Hub, they were fighting over a developted city.
You are true about the Merchant War, but California is the most populated state in the US, one of the largest ones and Fallout 1 was set in almost all of it. Only one city, the Hub, had some remarkable progress in it with Junktown, Boneyard and Necropolis lagging far behind. In Fallout 2 we have the NCR which is certainly worthy, then the Vault City which has only 100 people in there, Redding which is hardly an advanced town and New Reno which is even worse than it could be without its current system. Of course there is also San Fransisco as well, though it's more of a Chinese city.
Fallout 3 is set in a single city, the number one target in any nuclear war, I don't see sense in drawing comparisons between the two coasts to discredit Fallout 3. Not saying that you are trying it, of course.