Damn! I even triple posted...

Any enchantment that is added to your apparel, like resist fire, will be associated directly to your character. That has nothing to do with suppressing fire with the shield. It's no different than enchanting boots with 50% Resist Fire.
Yeah, I think the OP is missing the point that the shield is rather unique in that it is both a passive piece of armor (like boots or gauntlets) and potentially an active piece like a weapon. Even when it's not actively being wielded, it's still a hunk of metal or armor-like material covering prime body real estate (upper thigh, hip, part of the abdomen) -- compare it's geography, if you will, to the passive coverage of boots and the liklihood that its real estate will be targeted.
Generally, a shield's passive AR is equal to that of the equivalent material AR of boots + gauntlets, which makes sense when you consider the liklihood of the areas it covers being hit vs. the ones they cover.
Now if you actively use the shield to block, of course, you're really using it as much as a weapon and less as a defensive covering. You're now using it to parry, push back, create openings, cause imbalance, etc. And keep in mind that none of Block Perks are effective unless the shield is raised and, thus, one is actively using the shield.