Edit: Of the list below, only the last suggestion, Bloodlines, is close to what you originally asked about (it's over the shoulder third-person). But you mentioned Pillars of Eternity, so I included these others.
Planescape:Torment is widely considered the best RPG, ever, with Baldur's Gate 1 & 2 close behind. PST is unique, has a great storyline, and a lot of choice in terms of character development (roleplaying-wise). BG 1 & 2 have better tactical combat and good stories.
Ultima 7 is great and available on gog (as are the others I mentioned above). And there are both the original and enhanced editions of the 2 BG games, which purists hate, but I think are fine (you can do most of what the enhanced edition does with mods for the originals, FWIW).
I'm a big fan of the recent Shadowrun games. Shadowrun Returns was good, Dragonfall was great, and the recently released Hong Kong was decent. These are linear, though, so they may not be to your taste compared to New Vegas.
Also to get on the Obsidian track (the studio behind Pillars of Eternity and New Vegas), you might want to look at Alpha Protocol, Neverwinter Nights 2 + DLC, and Star Wars: Knights of the Old Republic 2. KotOR 1 is a good, linear RPG by old-school Bioware. KotOR 2 is, IMO a flawed masterpiece. There are some mods that really need to be installed to fix bugs and finish incomplete parts of the game. Obsidian has had a lot of problems with being pressured to ship too soon, and a lot of their older games show it. But if you're a fan of well-written RPGs, you won't be disappointed. They also recently released The Stick of Truth, a South Park RPG that has gotten a lot of positive reviews, but I haven't played it.
My last suggestion is Vampire the Masquerade:Bloodlines. This is one of those titles that wasn't particularly successful (Troika went out of business shortly after shipping, and were unable to provide bug fixes), but is loved by a lot of RPG fans. There's a well-regarded fan patch that's been getting updates for years, with purely bug fix or bug fix plus extra content versions.