I created a build around high charisma (10) and pacifying as many enemies as possible with the animal friend, wasteland whisperer, and intimidation perks. My intention was to be a pacifist character who tries to go through the wasteland with minimal combat. I have invested a point in each of these perks and I am now level 12, but I have only seen 1 opportunity to pacify an enemy so far in 14 hours of playtime. 1 of 2 things must be happening: (1) I am doing something wrong, or (2) these 3 perks are the most useless perks on the whole list. I even upped my perception and invested in awareness to see if all of the enemies that I am encountering are above my level (and therefore not able to be pacified), but many of the enemies I encounter appear to be lower level than me.
Could a kind soul please explain how pacification works? Do I need to be in VATS, and if so, is there something special I need to be doing in VATS to pacify? Do I need to be outside of VATS, and if so, is there something special I need to be doing to pacify outside of VATS? I use VATS about 50% of the time, and the only successful pacification was in VATS very early in the game.
Thanks for any help that you can provide on this.