More numerous music audio files
More recorded dialogue
More cut scene type embellishments ( not huge use necessarily, but added oomph put into some of the main story quest line points)
Stepped up resolution in the graphics including light and shadow dynamics
More varied game world, underwater animations etc.
The whole crafting setup for settlement creation has a lot more capacity for individual customization, much more versatile than Hearthfire
I've little doubt that DLC might also include some new things, with a music library expansion being one of them! Be interesting how big the game will actually be when the last DLC drops..... Hmmm don't even want to think about that sad day.....