If you commit a crime, resist arrest, and then yield the guard will talk to you and attempt to arrest you again.
As a side, I quite like the combination of buttons, makes me think I'm cowering (block) and yelling for mercy (activating).
Me to, makes sort of sense in a sword fight you go into a defensive stance and tell the other that you want the fight to stop. In a gunfight you put away your gun.
Friendly/ neutral npc you have hit will usually accept you yield, guards will try to arrest you again same as the police do.
I managed to hit the count of Skingrad with spells during a quest so he attacked me, but accepted my yield however a friendly sheep kept attacking the count making everything pretty confusing.