I was wondering where I could get all the Fallout 3 GNR Music. I wasn't sure if the songs are on iTunes or not. Could someone point me in the right direction?

I found them all, and more, on iTunes. You can look them up under FO3.

Even the purely instrumental songs too? Because I looked at iTunes and only see the songs with lyrics in them.

If you're on a PC, all you have to do is extract them from the BSA archive. They're in MP3 format.