The GECK is one of the most powerful game editors ever released to the public, I can find None that are as robust and sophisticated in my experience. That may be simply because TES4/Fo3/NV are RPGs and thus are very complex by their nature, and the GECK is the actual tool they used to build it (minus 1 or 2 things like lip sync). It has a steep learning curve, but once over that, you can do just about _anything_ that you put your imagination too.
Unfortunatley there are currently no good Full tutorials on how to use the GECK. Bethesda made some Excellent YouTube videos that will teach you some basics, and the WIKI as WillieSea pointed out, is a great resource when your stuck on something or need to fully understand something. At some point a more comprehensive manual will be made by someone I'm sure.
Miax