Spoilers:
after finishing the Soul Cairn / Valerica quest, I dismissed Serana for a bit before joining up again. Since rejoining however, the only dialogue options are the standard follower ones: browse inventory, wait here, and dismissal. All of her unique dialogue options are gone. I'm on my way to the ancestor glade now, and still no unique dialogues.
Dawnguard has been a horrific mess of bugs for me, with and without the unofficial patch, so I'd like to know whether I'm missing dialogue with her. (Now that I think about it, I don't think I have a pre-dismissal backup save....). Can anyone confirm?