Happy to provide some inspiration but be aware that as CurlyGreylox says there is a lot of trial and error and minute adjustments involved in order to get that first block in just the right position so that the rest will go where you want it without clipping. If it doesn't you have to store or move everything until you are back to that first block, move it and try again and keep doing that until you can get pieces where you want them. It wont always work though. What I did each time before deconstructing everything if it is close but not perfect was save first. If when I dismantled it and try again I cant get it any better I would go back to the saved game and just put up with "Good enough".
Also if a particular wall, floor or other item wont fit where you want it to due to clipping, try rotating it or using a similar sized item as they may fit. Especially with the smaller floor pieces I found some locations where none of them woudl fit except one of them but only in a specific orientation.
The concrete blocks are just one of the Shack Foundations for those who hadn't discovered that. Make sure you clear the tunnels of junk as there are a lot materials you will need there.
Other quick tips are for power generators an ideal spot is in the West bastion head all the way to the right until you pass the big room and get to the bottom of the stairs. That little room can easily take 3 small or two medium Gennys and has a convenient hook up point. The Entrance to the Armory is also a good place for them as well either as stand alone power or to link in to the main circuit with pylons and connectors.
Also when in the armory go into Workshop mode. Some of the items in there are not just decoration and can be moved to improve your defenses else where in the settlement, some of the other potentially useful defenses cant be moved though unfortunately