One of my characters is a pure Mage, and started with the following skill levels (which were intentionally gimped thru the questions as to allow maximum level):
Destruction 32, Illusion 32, Mysticism 33
Restoration 23, Alteration 23, Thaumaturgy 23
Etiquette 15, Mercantile 15, Medical 14, Dragonish 16, Daedric 16, Nymph 19
Maximum level = 31.07
I just gave him a break and decided to build a pure Berserker type, also intentionally gimped thru the questions:
Blunt 26, Critical Strike 26, Dodging 32
Running 16, Jumping 18, Climbing 20
Swimming 11, Medical 11, Streetwise 11, Giantish 11, Orcish 17, Centaurian 11
Maximum level = 32.60
The only thing that comes to my mind is that the mage had both his Intelligence and WIllpower at very high starting points (90 and 75), while the Berserker had only Endurance maximised (94) with Strength, Agility and Speed at mid-60's (I doubt this is the reason, but...).
Otherwise, it would appear that a combat oriented build will have a little higher max level than a pure magic build.