I haven't killed a single deathclaw, then again I don't stick with a char long enough to reach level 20, all I want is the armour, nothing more, killing deathclaws has never been my bag; I hunt NCR pigs from out of sight through the scope of a Gauss Rifle for glorious vengeance for my colleagues who died at Navarro, however I need the appropriate uniform and as an Enclave Officer Uniform never appears I go for the armour.
officers armour:
Spoiler hoover dam, joshua has it
on topic, if I didn't slaughter them at earliest convience I'd go do the quests but I hate them so meh,
The best explanation is they began mass production before the war just in case and had mass blueprints that have been found in ruins since they're defeat, so silver rush found these and improved upon them.