Everytime I go anywhere near USAF Satellite Station Olivia my game immediately exits itself and goes to desktop, no error box, nothing. My graphics card is up to date and even if I put on the lowest settings, it still crashes. WHY!?

No idea, but I had to abandon a character because it did that every time I entered the cell containing Sanctuary.

I don't know where the cell boundary is near Olivia, but that might be the trigger.

Try making a new character and immediately running over there, also try a previous save if you have one.

Unfortunately it could be something in the cell that causes a memory overflow, a graphics glitch, a mod conflict, a corrupted savegame... the phase of the moon, the wrong kind of grain sacrificed to Zorkon the Space God... darned near anything.

Do you have mods? I do know some of the armor/re-texture mods will cause this as soon as the armor/texture loads from armors.

I have a ghoul eye retexture and "scrapping annoying thing" mod, it still did it at the first time I played it without mods too, so it isn't the mods.