Try to shoot your opponent before airstomping or after he killed one of your team mate.
If you're up close with a player and dealt enough damage and if your ammo is empty, give it a try
That's about all the tips I can give you to airstomp, I never levelled it but I always found it fun to kill someone with the airstomp.
Map :
Pier 17 on crash site, at the back of the shopping mall, I got a double kill with an airstomp from the top.
Wall Street : from the top of the snipe/HMG building or top of spear if you're lucky
Most of my kills are flukes but I still keep airstomp in some classes for the fun of it