I've been finding Traders for my major settlements, but so far, I've only recruited three (Rylee, VaultTec Rep, the Scribe).
I know there are a couple of others around, but it seems that there aren't enough to go around, considering the sheer number of Settlements that can be established.
I once tried to designate an ordinary Settler as a Trader, but apparently, they don't have the code necessary to meet this function, as they don't become one when allocated to a vendor stall.
I don't even need named ones, just Trader would do.