I've tried adding reflect damage spells to NPCs, but they refuse to cast them in combat, even if it's the only spell they have. I suspect that, based on the magic effect code, NPCs might actually consider reflect damage a spell to restore the ReflectDamage actor value. Nothing I do causes the NPCs to start using the spells, but I would appreciate it if anyone could confirm my theory about the magic effect.
They won't use Spell Absorption spells or potions, either.